The Baylis–Hillman reaction is a carbon-carbon bond forming reaction between the α-position of an activated alkene and an aldehyde, or generally a carbon electrophile. Employing a nucleophilic catalyst, such as tertiary amine and phosphine, this reaction provides a densely functionalized product (e.g. functionalized allyl alcohol in the case of aldehyde as the electrophile). This reaction is also known as the Morita–Baylis–Hillman reaction or MBH reaction. It is named for the Japanese chemist Ken-ichi Morita, the British chemist Anthony B. Baylis and the German chemist Melville E. D. Hillman.
Links:
http://www.organic-chemistry.org/namedreactions/baylis-hillman-reaction.shtm
http://www.name-reaction.com/baylis-hillman-reaction
http://www.name-reaction.com/baylis-hillman-reaction
Further reading:
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